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1 day vs 3 day pass versus separate tickets

Going to europe for first time:
I can't seem to compare (buying separate tickets or a pass) right now as many place to place aren't available. I'm not clear on the 1 day pass in one country and then next option 3 day?
I fly into Munich 03 June 2014, train to linz, stay with friend for 5 days, train to barcelona, Spain for approx 5 days only need to get to sites one day then go to Aberdeen, Scotland for a week. Have a friend there to stay with and travel with - she lives there. Then train back to munich to return to Alaska. Would it be cheaper to get tickets there or get a eurail pass?
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