Castles and Peaks

We will be arriving in Munich on Jan 5 and would like to take a train to Bressanone, Brixen Italy where we will join our Italian friends to ski for 6 days in the Dolomites, We plan to return to Munich to tour castles on Jan 11th. Trying to find the right rail ticket to do this for 2 adults and 2 of our 24 year old children. Help is needed as I can't seem to find this round trip ticket on raileurope.
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